Surface-initiated mechano-ATRP as a convenient tool for tuning of bidisperse magnetorheological suspensions toward extreme kinetic stability

Surface-initiated ATRP modification of tissue culture substrates: poly(glycerol monomethacrylate) as an antifouling surface.

Surface-initiated atom transfer radical polymerization (SI-ATRP) can be used to produce conformal coatings of controlled thickness on virtually any surface, providing to it specific physico-chemical and biological properties. Here we have tackled the problem of modulating cell adhesion on typical culture substrates; tissue culture polystyrene (TCPS) offers a number of favorable properties (opti...

Surface Initiated Polymerizations via e-ATRP in Pure Water

Here we describe the combined process of surface modification with electrochemical atom transfer radical polymerization (e-ATRP) initiated from the surface of a modified gold-electrode in a pure aqueous solution without any additional supporting electrolyte. This approach allows for a very controlled growth of the polymer chains leading towards a steady increase in film thickness. Electrochemic...

Simulation for the Microstructure and Rheology in Bidisperse Magnetorheological Fluids

There are many ferromagnetic particles dispersed in carrier oil in magnetorheological fluids. Assuming Newtonian motion, the forces between particles of different radius, including magnetic interaction, viscous force and contact interaction, are obtained, and the corresponding model for motion of particles is proposed. Under an external magnetic field, the microstructures in bidisperse magnetor...

Chain Dynamics in Magnetorheological Suspensions

Magnetorheo]ogical (MR) fluids are colloidal suspensions of pammagnetic particles in a non-magnetic fluid. These fluids, along with their electrical analogues, electrorheologica] (ER) fluids, have been proposed as controllable fluids, for use in electromechanical devices such as dampers, clutches and brakes. [1] When exposed to an external magnetic field, the particles acquire dipole moments ag...

Development of a Molecular Kinetic Model and Tuning of its Required Kinetic Parameters for Thermal Cracking of Light Hydrocarbons